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Cs3CrSe4

高熵材料 HEA 传统材料 TRA

MP-ID: mp-3322475 · 空间群: Pnma (#62)

基础信息

化学式
Cs3CrSe4
MP-ID
mp-3322475
元素数
3
位点数
32
密度
4.1760
g/cm³
体积
1,219.25
ų
晶胞参数 a
10.1372
Å
晶胞参数 b
10.0882
Å
晶胞参数 c
11.9224
Å
α 角
90.00
°
β 角
90.00
°
γ 角
90.00
°
空间群
Pnma
点群
mmm
晶体系统
Orthorhombic
布拉维格子
Orthorhombic P
稳定性
是
堆积分数
0.5240

X 射线衍射

衍射图谱
横轴为 2θ (°),纵轴为相对强度,CuKa , λ=1.5406 Å
衍射峰(Top 24)
2θd (Å)Ihkl
11.49 7.7012 1.8 (0,1,1)
14.44 6.1323 13.6 (1,1,1)
14.86 5.9612 4.4 (0,0,2)
17.50 5.0686 2.3 (2,0,0)
19.03 4.6646 12.1 (2,0,1)
19.60 4.5291 21.1 (2,1,0)
21.04 4.2231 12.3 (1,2,1)
23.03 3.8615 58.0 (2,0,2)
23.10 3.8506 49.1 (0,2,2)
24.07 3.6976 17.4 (0,1,3)
24.69 3.6063 7.0 (2,1,2)
24.73 3.5996 50.0 (1,2,2)
24.90 3.5753 34.5 (2,2,0)
25.65 3.4737 30.4 (1,1,3)
27.56 3.2365 90.1 (0,3,1)
27.84 3.2041 72.1 (3,1,0)
27.95 3.1917 21.6 (1,3,0)
28.54 3.1274 100.0 (2,0,3)
28.85 3.0943 8.1 (3,1,1)
28.96 3.0831 14.4 (1,3,1)
29.12 3.0661 67.3 (2,2,2)
29.91 2.9872 67.5 (2,1,3)
29.95 2.9834 13.9 (1,2,3)
29.98 2.9806 34.7 (0,0,4)
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能量属性

形成能/原子
-1.09385
eV/atom
能量/原子
-19.54947
eV/atom
凸包距离
0.0000
eV/atom
未修正能量
-19.5495
eV/atom
体积/原子
38.10
ų
c/a 比
-

电子属性

金属性
金属
带隙
0
eV
直接带隙
否
导带底 CBM
N/A
eV

磁性属性

磁性
是
总磁矩
4.0006
μB
磁有序
FM
磁性位点数
4
磁化强度/体积
0.003280
μB/ų

弹性属性

弹性数据暂不开放

特征分析

组成概览

元素组成(原子分数)
组成信息
主元 / 基质元素
Se · 0.500
元素家族
Metalloid-Nonmetal
溶质分数
0.500
间隙分数
0.000

高熵合金特征

综合指标雷达(归一化)
元素类别占比
混合熵 ΔS/R
0.9743
高熵判据(>1.0 视为高熵)
混合熵 ΔS
8.1005
J/mol·K
Ω 参数
0.0000
Ω > 1.1 利于固溶体形成
原子尺寸错配 δr
40.387%
δr < 6.6% 利于单相固溶
电负性差 Δχ
0.8160
越小混合越稳定
价电子浓度 VEC
3.125
价电子浓度,影响相稳定性
混合焓 ΔH_mix
0.000
kJ/mol 且负值为放热混合
熵归一化
0.8869
固溶体倾向
0
相趋势
IM

传统材料特征

ROM 混合特征雷达
评级与分类
评级 Tier
B
评分
0.470
家族
Se-rich Multi-Component
基质元素
Se · 0.500

关联任务

关联的计算任务 ID(1 个)

引用参考

Materials Project 官方页面
https://materialsproject.org/materials/mp-3322475
参考引用

The crystal structure and related material properties of Cs3CrSe4 were obtained from the Materials Project database (MP-ID: mp-3322475, database version v2026.04.13).

文献引用

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

晶体结构 3D 渲染

加载 3D 结构...

样式: Ball & Stick
原始 CIF 数据
# generated using pymatgen
data_Cs3CrSe4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.13720352
_cell_length_b   10.08817539
_cell_length_c   11.92235542
_cell_angle_alpha   90.00000000
_cell_angle_beta   90.00000000
_cell_angle_gamma   90.00000000
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cs3CrSe4
_chemical_formula_sum   'Cs12 Cr4 Se16'
_cell_volume   1219.25025356
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.54327314  0.20617493  0.04008236  1.0
  Cs  Cs1  1  0.04327314  0.29382507  0.45991764  1.0
  Cs  Cs2  1  0.45672686  0.79382507  0.54008236  1.0
  Cs  Cs3  1  0.95672686  0.70617493  0.95991764  1.0
  Cs  Cs4  1  0.45672686  0.79382507  0.95991764  1.0
  Cs  Cs5  1  0.95672686  0.70617493  0.54008236  1.0
  Cs  Cs6  1  0.54327314  0.20617493  0.45991764  1.0
  Cs  Cs7  1  0.04327314  0.29382507  0.04008236  1.0
  Cs  Cs8  1  0.64980794  0.40920731  0.75000000  1.0
  Cs  Cs9  1  0.14980794  0.09079269  0.75000000  1.0
  Cs  Cs10  1  0.35019206  0.59079269  0.25000000  1.0
  Cs  Cs11  1  0.85019206  0.90920731  0.25000000  1.0
  Cr  Cr12  1  0.72256359  0.98269207  0.75000000  1.0
  Cr  Cr13  1  0.22256359  0.51730793  0.75000000  1.0
  Cr  Cr14  1  0.27743641  0.01730793  0.25000000  1.0
  Cr  Cr15  1  0.77743641  0.48269207  0.25000000  1.0
  Se  Se16  1  0.82846660  0.04865158  0.59307180  1.0
  Se  Se17  1  0.32846660  0.45134842  0.90692820  1.0
  Se  Se18  1  0.17153340  0.95134842  0.09307180  1.0
  Se  Se19  1  0.67153340  0.54865158  0.40692820  1.0
  Se  Se20  1  0.17153340  0.95134842  0.40692820  1.0
  Se  Se21  1  0.67153340  0.54865158  0.09307180  1.0
  Se  Se22  1  0.82846660  0.04865158  0.90692820  1.0
  Se  Se23  1  0.32846660  0.45134842  0.59307180  1.0
  Se  Se24  1  0.51481486  0.06664444  0.75000000  1.0
  Se  Se25  1  0.01481486  0.43335556  0.75000000  1.0
  Se  Se26  1  0.48518514  0.93335556  0.25000000  1.0
  Se  Se27  1  0.98518514  0.56664444  0.25000000  1.0
  Se  Se28  1  0.71000349  0.75943388  0.75000000  1.0
  Se  Se29  1  0.21000349  0.74056612  0.75000000  1.0
  Se  Se30  1  0.28999651  0.24056612  0.25000000  1.0
  Se  Se31  1  0.78999651  0.25943388  0.25000000  1.0
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