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BaMn4AlO7

High-Entropy Materials HEA

MP-ID: mp-1048458 · Space group: P6_3mc (#186)

Basic Information

Formula
BaMn4AlO7
MP-ID
mp-1048458
Elements
4
Sites
26
Density
4.7608
g/cm³
Volume
346.04
ų
Cell a
6.3085
Å
Cell b
6.3085
Å
Cell c
10.0403
Å
α Angle
90.00
°
β Angle
90.00
°
γ Angle
120.00
°
Space Group
P6_3mc
Point Group
6mm
Crystal System
Hexagonal
Bravais Lattice
Hexagonal P
Stability
No
Packing Fraction
0.7400

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
17.67 5.0202 7.5 (0,0,0,2)
18.49 4.7989 22.8 (1,0,-1,1)
24.07 3.6966 5.7 (1,0,-1,2)
28.29 3.1543 29.3 (2,-1,-1,0)
31.34 2.8539 61.7 (1,0,-1,3)
32.79 2.7317 3.9 (2,0,-2,0)
33.55 2.6708 72.5 (2,-1,-1,2)
34.01 2.6359 100.0 (2,0,-2,1)
35.77 2.5101 20.7 (0,0,0,4)
37.48 2.3994 12.9 (2,0,-2,2)
39.51 2.2809 13.8 (1,0,-1,4)
43.84 2.0650 1.9 (3,-1,-2,0)
44.81 2.0226 9.8 (3,-1,-2,1)
46.22 1.9641 5.8 (2,-1,-1,4)
47.62 1.9097 2.7 (3,-1,-2,2)
48.29 1.8848 4.5 (1,0,-1,5)
50.09 1.8211 5.1 (3,0,-3,0)
50.96 1.7919 2.5 (3,0,-3,1)
52.04 1.7574 26.1 (3,-1,-2,3)
53.53 1.7120 19.5 (3,0,-3,2)
54.86 1.6734 3.5 (0,0,0,6)
56.91 1.6179 28.9 (2,0,-2,5)
57.61 1.6000 3.4 (1,0,-1,6)
57.82 1.5947 14.6 (3,-1,-2,4)
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Energy Properties

Formation Energy/atom
-2.28570
eV/atom
Energy/atom
-8.20480
eV/atom
Energy above Hull
0.2160
eV/atom
Uncorrected Energy
-7.3217
eV/atom
Volume/atom
13.31
ų
c/a Ratio
1.5915

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
37.9794
μB
Mag. Ordering
FM
Mag. Sites
8
Magnetization/Volume
0.109750
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
O · 0.538
Element Family
Metalloid-Nonmetal
Solute Fraction
0.462
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
1.0906
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
9.0672
J/mol·K
Ω Parameter
3.2544
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
47.889%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
1.0066
smaller = more stable mixing
VEC
4.692
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
-1.799
kJ/mol; negative = exothermic mixing
Entropy Norm
0.7867
SS Former
0
Phase Tendency
IM

Related Tasks

Related computation task IDs (2)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-1048458
Reference Citation

The crystal structure and related material properties of BaMn4AlO7 were obtained from the Materials Project database (MP-ID: mp-1048458, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_BaMn4AlO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.30851590
_cell_length_b   6.30851590
_cell_length_c   10.04031100
_cell_angle_alpha   90.00000000
_cell_angle_beta   90.00000000
_cell_angle_gamma   119.99999894
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BaMn4AlO7
_chemical_formula_sum   'Ba2 Mn8 Al2 O14'
_cell_volume   346.04470284
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.66666700  0.33333300  0.52098800  1.0
  Ba  Ba1  1  0.33333300  0.66666700  0.02098800  1.0
  Mn  Mn2  1  0.82219900  0.17780100  0.19553800  1.0
  Mn  Mn3  1  0.64439800  0.82219900  0.69553800  1.0
  Mn  Mn4  1  0.17780100  0.35560200  0.69553800  1.0
  Mn  Mn5  1  0.82219900  0.64439800  0.19553800  1.0
  Mn  Mn6  1  0.35560200  0.17780100  0.19553800  1.0
  Mn  Mn7  1  0.17780100  0.82219900  0.69553800  1.0
  Mn  Mn8  1  0.00000000  0.00000000  0.44625200  1.0
  Mn  Mn9  1  0.00000000  0.00000000  0.94625200  1.0
  Al  Al10  1  0.66666700  0.33333300  0.88551900  1.0
  Al  Al11  1  0.33333300  0.66666700  0.38551900  1.0
  O  O12  1  0.81578000  0.18422000  0.99217300  1.0
  O  O13  1  0.63156100  0.81578000  0.49217300  1.0
  O  O14  1  0.18422000  0.36843900  0.49217300  1.0
  O  O15  1  0.81578000  0.63156100  0.99217300  1.0
  O  O16  1  0.36843900  0.18422000  0.99217300  1.0
  O  O17  1  0.18422000  0.81578000  0.49217300  1.0
  O  O18  1  0.00000000  0.00000000  0.73374200  1.0
  O  O19  1  0.00000000  0.00000000  0.23374200  1.0
  O  O20  1  0.47983700  0.52016300  0.26145500  1.0
  O  O21  1  0.95967400  0.47983700  0.76145500  1.0
  O  O22  1  0.52016300  0.04032600  0.76145500  1.0
  O  O23  1  0.47983700  0.95967400  0.26145500  1.0
  O  O24  1  0.52016300  0.47983700  0.76145500  1.0
  O  O25  1  0.04032600  0.52016300  0.26145500  1.0
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