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Li(FeO2)2

High-Entropy Materials HEA Traditional Materials TRA

MP-ID: mp-1178106 · Space group: Cc (#9)

Basic Information

Formula
Li(FeO2)2
MP-ID
mp-1178106
Elements
3
Sites
28
Density
4.3347
g/cm³
Volume
279.85
ų
Cell a
5.8473
Å
Cell b
5.8473
Å
Cell c
9.4152
Å
α Angle
89.73
°
β Angle
89.73
°
γ Angle
119.62
°
Space Group
Cc
Point Group
m
Crystal System
Monoclinic
Bravais Lattice
Monoclinic C
Stability
No
Packing Fraction
0.5240

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
18.85 4.7074 100.0 (0,0,0,2)
19.78 4.4879 57.2 (1,0,-1,1)
19.92 4.4580 51.5 (1,0,-1,-1)
19.94 4.4531 65.3 (1,-1,0,1)
25.69 3.4677 20.9 (1,0,-1,2)
25.86 3.4447 16.1 (1,-1,0,2)
25.90 3.4402 19.5 (1,0,-1,-2)
33.44 2.6800 19.7 (1,0,-1,3)
33.61 2.6661 19.3 (1,-1,0,3)
33.68 2.6609 18.6 (1,0,-1,-3)
35.31 2.5416 15.6 (2,0,-2,0)
35.52 2.5271 10.5 (2,-2,0,0)
35.86 2.5043 15.2 (1,1,-2,2)
36.09 2.4887 29.5 (2,-1,-1,2)
36.17 2.4836 15.2 (1,1,-2,-2)
36.24 2.4785 31.7 (2,-1,-1,-2)
36.55 2.4587 33.4 (2,0,-2,1)
36.70 2.4488 32.4 (2,0,-2,-1)
36.83 2.4407 26.0 (2,-2,0,1)
38.24 2.3537 11.2 (0,0,0,4)
40.19 2.2440 23.1 (2,0,-2,2)
40.47 2.2290 22.3 (2,0,-2,-2)
40.52 2.2265 19.2 (2,-2,0,2)
45.76 1.9829 35.1 (2,0,-2,3)
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Energy Properties

Formation Energy/atom
-1.65110
eV/atom
Energy/atom
-7.17121
eV/atom
Energy above Hull
0.0731
eV/atom
Uncorrected Energy
-6.1341
eV/atom
Volume/atom
9.99
ų
c/a Ratio
-

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
36.0006
μB
Mag. Ordering
FM
Mag. Sites
8
Magnetization/Volume
0.128640
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
O · 0.571
Element Family
Metalloid-Nonmetal
Solute Fraction
0.429
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
0.9557
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
7.9457
J/mol·K
Ω Parameter
2.9860
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
41.100%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
0.9730
smaller = more stable mixing
VEC
4.714
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
1.633
kJ/mol; negative = exothermic mixing
Entropy Norm
0.8699
SS Former
0
Phase Tendency
IM

Traditional Material Features

ROM Blended-Feature Radar
Rating & Classification
Tier
B
Score
0.460
Family
O-rich Multi-Component
Matrix Element
O · 0.571

Related Tasks

Related computation task IDs (1)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-1178106
Reference Citation

The crystal structure and related material properties of Li(FeO2)2 were obtained from the Materials Project database (MP-ID: mp-1178106, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_Li(FeO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.84733819
_cell_length_b   5.84733819
_cell_length_c   9.41520489
_cell_angle_alpha   89.73344558
_cell_angle_beta   89.73344558
_cell_angle_gamma   119.61718094
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li(FeO2)2
_chemical_formula_sum   'Li4 Fe8 O16'
_cell_volume   279.84700540
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.32746100  0.66778200  0.10557400  1.0
  Li  Li1  1  0.00201800  0.00701800  0.00341400  1.0
  Li  Li2  1  0.00701800  0.00201800  0.50341400  1.0
  Li  Li3  1  0.66778200  0.32746100  0.60557400  1.0
  Fe  Fe4  1  0.16846300  0.34107000  0.78736300  1.0
  Fe  Fe5  1  0.34103800  0.65782000  0.51443800  1.0
  Fe  Fe6  1  0.66044100  0.83106200  0.78704800  1.0
  Fe  Fe7  1  0.16860400  0.83116000  0.78607900  1.0
  Fe  Fe8  1  0.83116000  0.16860400  0.28607900  1.0
  Fe  Fe9  1  0.65782000  0.34103800  0.01443800  1.0
  Fe  Fe10  1  0.34107000  0.16846300  0.28736300  1.0
  Fe  Fe11  1  0.83106200  0.66044100  0.28704800  1.0
  O  O12  1  0.17581800  0.32802800  0.39889100  1.0
  O  O13  1  0.47572000  0.50849100  0.66083800  1.0
  O  O14  1  0.32944200  0.65895900  0.89676700  1.0
  O  O15  1  0.00342100  0.01116400  0.69128000  1.0
  O  O16  1  0.01116400  0.00342100  0.19128000  1.0
  O  O17  1  0.67274000  0.82648400  0.40100300  1.0
  O  O18  1  0.04245300  0.50827900  0.65722600  1.0
  O  O19  1  0.48809800  0.95432800  0.65586900  1.0
  O  O20  1  0.83716400  0.17515800  0.90029400  1.0
  O  O21  1  0.17515800  0.83716400  0.40029400  1.0
  O  O22  1  0.50827900  0.04245300  0.15722600  1.0
  O  O23  1  0.95432800  0.48809800  0.15586900  1.0
  O  O24  1  0.65895900  0.32944200  0.39676700  1.0
  O  O25  1  0.32802800  0.17581800  0.89889100  1.0
  O  O26  1  0.50849100  0.47572000  0.16083800  1.0
  O  O27  1  0.82648400  0.67274000  0.90100300  1.0
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