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CsAs5Pd9

High-Entropy Materials HEA Traditional Materials TRA

MP-ID: mp-3291613 · Space group: P6_3/mmc (#194)

Basic Information

Formula
CsAs5Pd9
MP-ID
mp-3291613
Elements
3
Sites
30
Density
8.6426
g/cm³
Volume
563.07
ų
Cell a
7.1875
Å
Cell b
7.1875
Å
Cell c
12.5857
Å
α Angle
90.00
°
β Angle
90.00
°
γ Angle
120.00
°
Space Group
P6_3/mmc
Point Group
6/mmm
Crystal System
Hexagonal
Bravais Lattice
Hexagonal P
Stability
Yes
Packing Fraction
0.7400

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
14.07 6.2928 15.1 (0,0,0,2)
14.23 6.2245 60.6 (1,0,-1,0)
25.61 3.4789 10.5 (1,0,-1,3)
28.37 3.1464 2.1 (0,0,0,4)
28.60 3.1207 81.5 (2,-1,-1,2)
28.68 3.1123 38.9 (2,0,-2,0)
31.87 2.8081 47.3 (1,0,-1,4)
32.08 2.7897 100.0 (2,0,-2,2)
35.93 2.4996 6.3 (2,0,-2,3)
38.01 2.3673 6.3 (2,-1,-1,4)
38.26 2.3527 1.9 (3,-1,-2,0)
38.26 2.3527 3.8 (2,1,-3,0)
38.58 2.3336 15.6 (1,0,-1,5)
38.95 2.3126 13.7 (3,-1,-2,1)
38.95 2.3126 6.9 (1,2,-3,1)
40.78 2.2127 97.0 (2,0,-2,4)
40.95 2.2037 9.1 (3,-1,-2,2)
40.95 2.2037 18.2 (2,1,-3,2)
43.13 2.0976 31.1 (0,0,0,6)
43.62 2.0749 3.5 (3,0,-3,0)
43.62 2.0749 1.8 (0,3,-3,0)
44.13 2.0520 75.4 (3,-1,-2,3)
44.24 2.0472 26.1 (3,0,-3,1)
44.24 2.0472 13.0 (0,3,-3,1)
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Energy Properties

Formation Energy/atom
-0.44100
eV/atom
Energy/atom
-20.79368
eV/atom
Energy above Hull
0.0000
eV/atom
Uncorrected Energy
-20.7937
eV/atom
Volume/atom
18.77
ų
c/a Ratio
1.7511

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
No
Total Mag. Moment
0.0023
μB
Mag. Ordering
NM
Mag. Sites
0
Magnetization/Volume
0.000000
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
Pd · 0.600
Element Family
4d-TM
Solute Fraction
0.400
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
0.8532
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
7.0938
J/mol·K
Ω Parameter
0.0000
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
24.802%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
0.3501
smaller = more stable mixing
VEC
7.067
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
0.000
kJ/mol; negative = exothermic mixing
Entropy Norm
0.7766
SS Former
0
Phase Tendency
IM

Traditional Material Features

ROM Blended-Feature Radar
Rating & Classification
Tier
B
Score
0.527
Family
Pd-rich Multi-Component
Matrix Element
Pd · 0.600

Related Tasks

Related computation task IDs (1)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-3291613
Reference Citation

The crystal structure and related material properties of CsAs5Pd9 were obtained from the Materials Project database (MP-ID: mp-3291613, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_CsAs5Pd9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.18747505
_cell_length_b   7.18747428
_cell_length_c   12.58568091
_cell_angle_alpha   90.00000000
_cell_angle_beta   90.00000000
_cell_angle_gamma   120.00000355
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CsAs5Pd9
_chemical_formula_sum   'Cs2 As10 Pd18'
_cell_volume   563.06688448
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.00000000  0.00000000  0.00000000  1.0
  Cs  Cs1  1  0.00000000  0.00000000  0.50000000  1.0
  As  As2  1  0.81937224  0.18062776  0.25000000  1.0
  As  As3  1  0.63874348  0.81937224  0.75000000  1.0
  As  As4  1  0.18062776  0.36125652  0.75000000  1.0
  As  As5  1  0.81937224  0.63874348  0.25000000  1.0
  As  As6  1  0.36125652  0.18062776  0.25000000  1.0
  As  As7  1  0.18062776  0.81937224  0.75000000  1.0
  As  As8  1  0.33333300  0.66666700  0.05569057  1.0
  As  As9  1  0.66666700  0.33333300  0.55569057  1.0
  As  As10  1  0.66666700  0.33333300  0.94430943  1.0
  As  As11  1  0.33333300  0.66666700  0.44430943  1.0
  Pd  Pd12  1  0.53290930  0.46709070  0.10605914  1.0
  Pd  Pd13  1  0.06581859  0.53290930  0.60605914  1.0
  Pd  Pd14  1  0.46709070  0.93418141  0.60605914  1.0
  Pd  Pd15  1  0.53290930  0.06581859  0.10605914  1.0
  Pd  Pd16  1  0.93418141  0.46709070  0.10605914  1.0
  Pd  Pd17  1  0.06581859  0.53290930  0.89394086  1.0
  Pd  Pd18  1  0.46709070  0.93418141  0.89394086  1.0
  Pd  Pd19  1  0.46709070  0.53290930  0.60605914  1.0
  Pd  Pd20  1  0.46709070  0.53290930  0.89394086  1.0
  Pd  Pd21  1  0.53290930  0.46709070  0.39394086  1.0
  Pd  Pd22  1  0.93418141  0.46709070  0.39394086  1.0
  Pd  Pd23  1  0.53290930  0.06581859  0.39394086  1.0
  Pd  Pd24  1  0.20212465  0.79787535  0.25000000  1.0
  Pd  Pd25  1  0.40424930  0.20212465  0.75000000  1.0
  Pd  Pd26  1  0.79787535  0.59575070  0.75000000  1.0
  Pd  Pd27  1  0.20212465  0.40424930  0.25000000  1.0
  Pd  Pd28  1  0.59575070  0.79787535  0.25000000  1.0
  Pd  Pd29  1  0.79787535  0.20212465  0.75000000  1.0
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