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La5GeAsIr

High-Entropy Materials HEA

MP-ID: mp-3297301 · Space group: P1 (#1)

Basic Information

Formula
La5GeAsIr
MP-ID
mp-3297301
Elements
4
Sites
32
Density
7.4201
g/cm³
Volume
925.87
ų
Cell a
8.2107
Å
Cell b
8.9216
Å
Cell c
12.6395
Å
α Angle
89.94
°
β Angle
89.86
°
γ Angle
90.01
°
Space Group
P1
Point Group
1
Crystal System
Triclinic
Bravais Lattice
Triclinic P
Stability
Yes
Packing Fraction
0.5240

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
12.84 6.8933 23.3 (1,0,1)
12.87 6.8775 21.8 (1,0,-1)
14.01 6.3197 45.6 (0,0,2)
14.66 6.0418 6.6 (1,-1,0)
14.66 6.0412 6.6 (1,1,0)
17.69 5.0141 2.3 (1,0,2)
17.73 5.0020 2.6 (1,0,-2)
19.90 4.4608 27.9 (0,2,0)
20.31 4.3726 2.9 (1,1,2)
20.32 4.3695 2.7 (1,-1,2)
20.35 4.3648 2.7 (1,-1,-2)
20.36 4.3613 2.5 (1,1,-2)
21.65 4.1053 2.4 (2,0,0)
22.79 3.9017 1.1 (2,0,-1)
23.71 3.7523 4.9 (1,0,3)
23.75 3.7459 1.0 (1,2,1)
23.76 3.7447 4.9 (1,0,-3)
23.77 3.7437 1.1 (1,-2,-1)
25.85 3.4467 10.7 (2,0,2)
25.91 3.4388 10.1 (2,0,-2)
26.74 3.3341 17.6 (1,2,2)
26.76 3.3314 16.9 (1,-2,2)
26.77 3.3308 17.4 (1,-2,-2)
26.79 3.3276 16.6 (1,2,-2)
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Energy Properties

Formation Energy/atom
-1.03765
eV/atom
Energy/atom
-29.74550
eV/atom
Energy above Hull
0.0000
eV/atom
Uncorrected Energy
-29.7455
eV/atom
Volume/atom
28.93
ų
c/a Ratio
-

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
No
Total Mag. Moment
0.0304
μB
Mag. Ordering
NM
Mag. Sites
0
Magnetization/Volume
0.000030
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
La · 0.625
Element Family
Lanthanide
Solute Fraction
0.375
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
1.0735
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
8.9254
J/mol·K
Ω Parameter
0.4919
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
20.212%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
0.5014
smaller = more stable mixing
VEC
3.875
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
-24.960
kJ/mol; negative = exothermic mixing
Entropy Norm
0.7744
SS Former
0
Phase Tendency
AM

Related Tasks

Related computation task IDs (1)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-3297301
Reference Citation

The crystal structure and related material properties of La5GeAsIr were obtained from the Materials Project database (MP-ID: mp-3297301, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_La5GeAsIr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.21069173
_cell_length_b   8.92157275
_cell_length_c   12.63949782
_cell_angle_alpha   89.93610993
_cell_angle_beta   89.85630590
_cell_angle_gamma   90.00578841
_symmetry_Int_Tables_number   1
_chemical_formula_structural   La5GeAsIr
_chemical_formula_sum   'La20 Ge4 As4 Ir4'
_cell_volume   925.86858587
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.67186875  0.74932436  0.71489531  1.0
  La  La1  1  0.32766381  0.25104537  0.28495578  1.0
  La  La2  1  0.17192423  0.25058116  0.78608582  1.0
  La  La3  1  0.82798500  0.74886333  0.21366192  1.0
  La  La4  1  0.14776426  0.75010772  0.79344485  1.0
  La  La5  1  0.84987424  0.25121587  0.20646655  1.0
  La  La6  1  0.64737420  0.24993566  0.70619812  1.0
  La  La7  1  0.35520958  0.74914897  0.29364775  1.0
  La  La8  1  0.54127221  0.74825843  0.99936014  1.0
  La  La9  1  0.46088277  0.25119299  0.00157002  1.0
  La  La10  1  0.03807311  0.25203871  0.50161916  1.0
  La  La11  1  0.95988391  0.74846377  0.49969640  1.0
  La  La12  1  0.81923009  0.46452052  0.92973505  1.0
  La  La13  1  0.18199853  0.53444831  0.06730402  1.0
  La  La14  1  0.31978126  0.53572817  0.57286365  1.0
  La  La15  1  0.18120506  0.96537494  0.07122903  1.0
  La  La16  1  0.67984874  0.46421533  0.43117937  1.0
  La  La17  1  0.81886137  0.03475495  0.93268111  1.0
  La  La18  1  0.67983709  0.03539458  0.42691026  1.0
  La  La19  1  0.31961996  0.96539822  0.56919193  1.0
  Ge  Ge20  1  0.55994701  0.00552008  0.17119736  1.0
  Ge  Ge21  1  0.94108997  0.49382949  0.67022562  1.0
  Ge  Ge22  1  0.55899414  0.49410011  0.17174084  1.0
  Ge  Ge23  1  0.43953732  0.50602592  0.82825368  1.0
  As  As24  1  0.94247627  0.00575339  0.67148411  1.0
  As  As25  1  0.05924255  0.99376158  0.32876115  1.0
  As  As26  1  0.44057941  0.99446159  0.82692788  1.0
  As  As27  1  0.05781358  0.50652194  0.32812573  1.0
  Ir  Ir28  1  0.93153736  0.75155104  0.98433302  1.0
  Ir  Ir29  1  0.06895071  0.24775671  0.01605750  1.0
  Ir  Ir30  1  0.42944133  0.24845049  0.51455349  1.0
  Ir  Ir31  1  0.57023219  0.75225527  0.48564537  1.0
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