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LiCu2F4

High-Entropy Materials HEA Traditional Materials TRA

MP-ID: mp-752742 · Space group: P2_1/m (#11)

Basic Information

Formula
LiCu2F4
MP-ID
mp-752742
Elements
3
Sites
14
Density
4.4518
g/cm³
Volume
156.68
ų
Cell a
9.8628
Å
Cell b
3.0186
Å
Cell c
5.2884
Å
α Angle
84.36
°
β Angle
90.00
°
γ Angle
90.00
°
Space Group
P2_1/m
Point Group
2/m
Crystal System
Monoclinic
Bravais Lattice
Monoclinic P
Stability
No
Packing Fraction
0.5240

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
16.85 5.2628 1.3 (0,0,1)
17.99 4.9314 99.7 (2,0,0)
19.11 4.6431 72.2 (1,0,1)
24.74 3.5985 1.5 (2,0,1)
29.74 3.0040 43.8 (0,1,0)
31.12 2.8736 9.6 (1,1,0)
32.10 2.7883 100.0 (3,0,1)
32.85 2.7268 33.5 (0,1,1)
34.07 2.6314 24.1 (0,0,2)
34.11 2.6282 2.9 (1,1,1)
34.98 2.5655 2.6 (2,1,0)
35.30 2.5425 3.4 (1,0,2)
35.85 2.5050 65.5 (0,1,-1)
36.44 2.4657 3.3 (4,0,0)
37.03 2.4280 24.2 (1,1,-1)
37.70 2.3863 2.2 (2,1,1)
38.79 2.3216 19.2 (2,0,2)
40.39 2.2334 40.7 (2,1,-1)
40.40 2.2328 21.2 (4,0,1)
40.69 2.2176 17.8 (3,1,0)
43.10 2.0988 11.9 (3,1,1)
43.43 2.0835 23.6 (0,1,2)
44.44 2.0385 15.1 (1,1,2)
45.52 1.9925 14.2 (3,1,-1)
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Energy Properties

Formation Energy/atom
-2.00439
eV/atom
Energy/atom
-4.54233
eV/atom
Energy above Hull
0.0639
eV/atom
Uncorrected Energy
-4.2783
eV/atom
Volume/atom
11.19
ų
c/a Ratio
-

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
2.0006
μB
Mag. Ordering
FM
Mag. Sites
4
Magnetization/Volume
0.012770
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
F · 0.571
Element Family
Metalloid-Nonmetal
Solute Fraction
0.429
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
0.9557
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
7.9457
J/mol·K
Ω Parameter
3.9210
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
49.735%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
1.2147
smaller = more stable mixing
VEC
6.143
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
-0.980
kJ/mol; negative = exothermic mixing
Entropy Norm
0.8699
SS Former
0
Phase Tendency
IM

Traditional Material Features

ROM Blended-Feature Radar
Rating & Classification
Tier
B
Score
0.520
Family
F-rich Multi-Component
Matrix Element
F · 0.571

Related Tasks

Related computation task IDs (2)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-752742
Reference Citation

The crystal structure and related material properties of LiCu2F4 were obtained from the Materials Project database (MP-ID: mp-752742, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_LiCu2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.86276100
_cell_length_b   3.01857500
_cell_length_c   5.28836996
_cell_angle_alpha   84.35998593
_cell_angle_beta   90.00000000
_cell_angle_gamma   90.00000000
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiCu2F4
_chemical_formula_sum   'Li2 Cu4 F8'
_cell_volume   156.68044195
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.25000000  0.96294500  0.22181700  1.0
  Li  Li1  1  0.75000000  0.03705500  0.77818300  1.0
  Cu  Cu2  1  0.07460600  0.64134100  0.73493600  1.0
  Cu  Cu3  1  0.42539400  0.64134100  0.73493600  1.0
  Cu  Cu4  1  0.57460600  0.35865900  0.26506400  1.0
  Cu  Cu5  1  0.92539400  0.35865900  0.26506400  1.0
  F  F6  1  0.61696100  0.67555600  0.58146400  1.0
  F  F7  1  0.88303900  0.67555600  0.58146400  1.0
  F  F8  1  0.25000000  0.57379400  0.92929500  1.0
  F  F9  1  0.75000000  0.42620600  0.07070500  1.0
  F  F10  1  0.11696100  0.32444400  0.41853600  1.0
  F  F11  1  0.38303900  0.32444400  0.41853600  1.0
  F  F12  1  0.50000000  0.00000000  0.00000000  1.0
  F  F13  1  0.00000000  0.00000000  0.00000000  1.0
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