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Cu2OF2

High-Entropy Materials HEA Traditional Materials TRA

MP-ID: mp-753831 · Space group: C2/c (#15)

Basic Information

Formula
Cu2OF2
MP-ID
mp-753831
Elements
3
Sites
30
Density
5.4425
g/cm³
Volume
331.51
ų
Cell a
5.2240
Å
Cell b
5.2240
Å
Cell c
13.9594
Å
α Angle
88.36
°
β Angle
88.36
°
γ Angle
60.54
°
Space Group
C2/c
Point Group
2/m
Crystal System
Monoclinic
Bravais Lattice
Monoclinic C
Stability
No
Packing Fraction
0.5240

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
19.52 4.5478 2.7 (1,0,-1,0)
19.69 4.5094 4.1 (1,1,-2,0)
23.13 3.8455 32.2 (1,1,-2,2)
23.53 3.7809 48.1 (1,0,-1,-2)
27.20 3.2790 9.7 (1,0,-1,3)
27.66 3.2247 1.5 (1,0,-1,-3)
32.08 2.7902 100.0 (1,0,-1,4)
32.98 2.7158 45.0 (1,1,-2,-4)
34.05 2.6332 51.4 (1,-1,0,0)
34.35 2.6108 74.1 (2,1,-3,0)
34.67 2.5875 12.1 (1,-1,0,1)
35.15 2.5531 5.0 (2,1,-3,-1)
36.47 2.4635 5.2 (1,-1,0,2)
37.11 2.4224 2.8 (2,1,-3,-2)
37.53 2.3963 4.0 (1,0,-1,5)
38.72 2.3253 12.2 (0,0,0,6)
39.08 2.3051 14.7 (2,1,-3,3)
39.32 2.2914 9.2 (1,-1,0,3)
39.64 2.2739 1.1 (2,0,-2,0)
39.99 2.2547 1.7 (2,2,-4,0)
40.09 2.2492 4.4 (2,1,-3,-3)
40.29 2.2384 2.0 (2,0,-2,-1)
41.57 2.1727 9.4 (2,0,-2,2)
42.54 2.1249 1.7 (2,2,-4,-2)
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Energy Properties

Formation Energy/atom
-1.38319
eV/atom
Energy/atom
-4.77830
eV/atom
Energy above Hull
0.0805
eV/atom
Uncorrected Energy
-4.4561
eV/atom
Volume/atom
11.05
ų
c/a Ratio
-

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
9.6240
μB
Mag. Ordering
FM
Mag. Sites
18
Magnetization/Volume
0.029030
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
Cu · 0.400
Element Family
3d-TM
Solute Fraction
0.600
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
1.0549
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
8.7706
J/mol·K
Ω Parameter
0.0000
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
44.184%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
0.9515
smaller = more stable mixing
VEC
7.200
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
0.000
kJ/mol; negative = exothermic mixing
Entropy Norm
0.9602
SS Former
0
Phase Tendency
IM

Traditional Material Features

ROM Blended-Feature Radar
Rating & Classification
Tier
B
Score
0.499
Family
Cu-rich Multi-Component
Matrix Element
Cu · 0.400

Related Tasks

Related computation task IDs (3)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-753831
Reference Citation

The crystal structure and related material properties of Cu2OF2 were obtained from the Materials Project database (MP-ID: mp-753831, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_Cu2OF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.22404277
_cell_length_b   5.22404277
_cell_length_c   13.95934723
_cell_angle_alpha   88.36202850
_cell_angle_beta   88.36202850
_cell_angle_gamma   60.53685378
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cu2OF2
_chemical_formula_sum   'Cu12 O6 F12'
_cell_volume   331.50896779
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.04606100  0.93851200  0.65244200  1.0
  Cu  Cu1  1  0.93851200  0.04606100  0.15244200  1.0
  Cu  Cu2  1  0.41686500  0.31034000  0.81746300  1.0
  Cu  Cu3  1  0.36385600  0.33227000  0.51478800  1.0
  Cu  Cu4  1  0.31034000  0.41686500  0.31746300  1.0
  Cu  Cu5  1  0.33227000  0.36385600  0.01478800  1.0
  Cu  Cu6  1  0.66773000  0.63614400  0.98521200  1.0
  Cu  Cu7  1  0.68966000  0.58313500  0.68253700  1.0
  Cu  Cu8  1  0.63614400  0.66773000  0.48521200  1.0
  Cu  Cu9  1  0.58313500  0.68966000  0.18253700  1.0
  Cu  Cu10  1  0.06148800  0.95393900  0.84755800  1.0
  Cu  Cu11  1  0.95393900  0.06148800  0.34755800  1.0
  O  O12  1  0.37668200  0.60781500  0.91179100  1.0
  O  O13  1  0.60781500  0.37668200  0.41179100  1.0
  O  O14  1  0.39218500  0.62331800  0.58820900  1.0
  O  O15  1  0.62331800  0.39218500  0.08820900  1.0
  O  O16  1  0.77543700  0.22456300  0.75000000  1.0
  O  O17  1  0.22456300  0.77543700  0.25000000  1.0
  F  F18  1  0.01944500  0.62846800  0.73679000  1.0
  F  F19  1  0.62846800  0.01944500  0.23679000  1.0
  F  F20  1  0.73203700  0.94012400  0.91795500  1.0
  F  F21  1  0.94012400  0.73203700  0.41795500  1.0
  F  F22  1  0.68694000  0.90459600  0.58597600  1.0
  F  F23  1  0.90459600  0.68694000  0.08597600  1.0
  F  F24  1  0.09540400  0.31306000  0.91402400  1.0
  F  F25  1  0.31306000  0.09540400  0.41402400  1.0
  F  F26  1  0.05987600  0.26796300  0.58204500  1.0
  F  F27  1  0.26796300  0.05987600  0.08204500  1.0
  F  F28  1  0.37153200  0.98055500  0.76321000  1.0
  F  F29  1  0.98055500  0.37153200  0.26321000  1.0
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