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Sm(FeO2)2

High-Entropy Materials HEA Traditional Materials TRA

MP-ID: mp-755338 · Space group: R-3m (#166)

Basic Information

Formula
Sm(FeO2)2
MP-ID
mp-755338
Elements
3
Sites
7
Density
5.8302
g/cm³
Volume
92.86
ų
Cell a
3.6071
Å
Cell b
8.4970
Å
Cell c
3.6108
Å
α Angle
102.27
°
β Angle
59.94
°
γ Angle
102.25
°
Space Group
R-3m
Point Group
-3m
Crystal System
Trigonal
Bravais Lattice
Trigonal R
Stability
No
Packing Fraction
0.7400

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
10.74 8.2376 97.9 (0,1,0)
21.58 4.1188 91.4 (0,2,0)
28.78 3.1016 89.3 (1,-1,1)
28.79 3.1005 89.9 (0,0,1)
28.82 3.0976 89.7 (1,0,0)
32.09 2.7894 72.5 (1,-2,1)
32.10 2.7885 72.0 (0,1,1)
32.12 2.7869 72.0 (1,1,0)
32.61 2.7459 100.0 (0,3,0)
33.93 2.6423 66.1 (1,1,1)
33.93 2.6417 66.0 (0,2,-1)
33.97 2.6392 65.9 (1,-2,0)
38.46 2.3404 8.9 (1,-3,1)
38.47 2.3398 8.8 (0,2,1)
38.49 2.3391 8.8 (1,2,0)
41.07 2.1975 14.1 (1,2,1)
41.08 2.1972 14.2 (0,3,-1)
41.11 2.1956 14.1 (1,-3,0)
46.86 1.9386 41.3 (1,-4,1)
46.87 1.9383 41.5 (0,3,1)
46.88 1.9380 41.4 (1,3,0)
49.99 1.8245 3.8 (1,3,1)
49.99 1.8244 3.8 (0,4,-1)
50.02 1.8233 3.8 (1,-4,0)
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Energy Properties

Formation Energy/atom
-2.35225
eV/atom
Energy/atom
-8.27375
eV/atom
Energy above Hull
0.0738
eV/atom
Uncorrected Energy
-7.2366
eV/atom
Volume/atom
13.27
ų
c/a Ratio
1.0010

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
9.0000
μB
Mag. Ordering
FM
Mag. Sites
4
Magnetization/Volume
0.096920
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
O · 0.571
Element Family
Metalloid-Nonmetal
Solute Fraction
0.429
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
0.9557
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
7.9457
J/mol·K
Ω Parameter
0.0000
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
47.706%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
0.9282
smaller = more stable mixing
VEC
5.429
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
0.000
kJ/mol; negative = exothermic mixing
Entropy Norm
0.8699
SS Former
0
Phase Tendency
IM

Traditional Material Features

ROM Blended-Feature Radar
Rating & Classification
Tier
C
Score
0.433
Family
O-rich Multi-Component
Matrix Element
O · 0.571

Related Tasks

Related computation task IDs (1)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-755338
Reference Citation

The crystal structure and related material properties of Sm(FeO2)2 were obtained from the Materials Project database (MP-ID: mp-755338, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_Sm(FeO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.60713212
_cell_length_b   8.49698447
_cell_length_c   3.61075253
_cell_angle_alpha   102.27333190
_cell_angle_beta   59.94424752
_cell_angle_gamma   102.25236782
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sm(FeO2)2
_chemical_formula_sum   'Sm1 Fe2 O4'
_cell_volume   92.86413991
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.00006400  0.99998800  0.00004300  1.0
  Fe  Fe1  1  0.21106200  0.63383000  0.21091800  1.0
  Fe  Fe2  1  0.78893500  0.36616900  0.78898100  1.0
  O  O3  1  0.12669700  0.38178800  0.12724000  1.0
  O  O4  1  0.28983700  0.87026000  0.29023800  1.0
  O  O5  1  0.71025100  0.12974000  0.70984000  1.0
  O  O6  1  0.87315400  0.61822500  0.87274000  1.0
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