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Li4Co3O3F4

High-Entropy Materials HEA

MP-ID: mp-759580 · Space group: I4/mmm (#139)

Basic Information

Formula
Li4Co3O3F4
MP-ID
mp-759580
Elements
4
Sites
14
Density
4.1746
g/cm³
Volume
130.69
ų
Cell a
15.1371
Å
Cell b
15.1371
Å
Cell c
15.1371
Å
α Angle
168.81
°
β Angle
168.81
°
γ Angle
15.86
°
Space Group
I4/mmm
Point Group
4/mmm
Crystal System
Tetragonal
Bravais Lattice
Tetragonal I
Stability
No
Packing Fraction
0.7400

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 22)
2θd (Å)Ihkl
5.90 14.9925 100.0 (1,1,-1)
11.81 7.4962 1.2 (2,2,-2)
17.75 4.9975 1.6 (3,3,-3)
30.42 2.9383 1.7 (1,0,0)
31.60 2.8315 1.1 (2,1,-1)
33.84 2.6489 10.4 (3,2,-2)
35.94 2.4988 3.7 (6,6,-6)
36.98 2.4310 3.0 (4,3,-3)
40.84 2.2097 6.6 (5,4,-4)
42.19 2.1418 7.9 (7,7,-7)
43.34 2.0877 15.7 (0,0,1)
43.78 2.0678 3.5 (1,1,0)
57.53 1.6021 3.2 (6,6,-5)
62.08 1.4950 8.5 (7,7,-6)
62.96 1.4762 4.3 (1,-1,1)
63.30 1.4691 1.1 (2,0,0)
67.27 1.3918 1.2 (10,9,-9)
73.43 1.2895 1.9 (3,2,-1)
74.68 1.2710 1.4 (7,5,-5)
75.32 1.2618 1.1 (4,3,-2)
77.81 1.2275 1.6 (5,4,-3)
78.73 1.2155 3.8 (8,6,-6)
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Energy Properties

Formation Energy/atom
-2.26991
eV/atom
Energy/atom
-5.95121
eV/atom
Energy above Hull
0.0834
eV/atom
Uncorrected Energy
-5.3210
eV/atom
Volume/atom
9.34
ų
c/a Ratio
1.0000

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
9.0096
μB
Mag. Ordering
FM
Mag. Sites
4
Magnetization/Volume
0.068940
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
Li · 0.286
Element Family
Alkali-AlkEarth
Solute Fraction
0.714
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
1.3761
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
11.4405
J/mol·K
Ω Parameter
0.4936
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
45.435%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
1.2468
smaller = more stable mixing
VEC
4.500
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
-12.413
kJ/mol; negative = exothermic mixing
Entropy Norm
0.9926
SS Former
0
Phase Tendency
IM

Related Tasks

Related computation task IDs (2)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-759580
Reference Citation

The crystal structure and related material properties of Li4Co3O3F4 were obtained from the Materials Project database (MP-ID: mp-759580, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_Li4Co3O3F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.13713565
_cell_length_b   15.13713565
_cell_length_c   15.13713565
_cell_angle_alpha   168.80673625
_cell_angle_beta   168.80673625
_cell_angle_gamma   15.85504417
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li4Co3O3F4
_chemical_formula_sum   'Li4 Co3 O3 F4'
_cell_volume   130.69147579
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.14767500  0.14767500  0.00000000  1.0
  Li  Li1  1  0.71659500  0.71659500  0.00000000  1.0
  Li  Li2  1  0.28340500  0.28340500  0.00000000  1.0
  Li  Li3  1  0.85232500  0.85232500  0.00000000  1.0
  Co  Co4  1  0.42605200  0.42605200  0.00000000  1.0
  Co  Co5  1  0.00000000  0.00000000  0.00000000  1.0
  Co  Co6  1  0.57394800  0.57394800  0.00000000  1.0
  O  O7  1  0.92450500  0.92450500  0.00000000  1.0
  O  O8  1  0.50000000  0.50000000  0.00000000  1.0
  O  O9  1  0.07549500  0.07549500  0.00000000  1.0
  F  F10  1  0.64927300  0.64927300  0.00000000  1.0
  F  F11  1  0.21622500  0.21622500  0.00000000  1.0
  F  F12  1  0.78377500  0.78377500  0.00000000  1.0
  F  F13  1  0.35072700  0.35072700  0.00000000  1.0
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