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Mn12O7F17

High-Entropy Materials HEA Traditional Materials TRA

MP-ID: mp-760898 · Space group: P1 (#1)

Basic Information

Formula
Mn12O7F17
MP-ID
mp-760898
Elements
3
Sites
36
Density
4.1621
g/cm³
Volume
436.56
ų
Cell a
4.7683
Å
Cell b
5.7643
Å
Cell c
15.8886
Å
α Angle
89.80
°
β Angle
89.47
°
γ Angle
88.60
°
Space Group
P1
Point Group
1
Crystal System
Triclinic
Bravais Lattice
Triclinic P
Stability
No
Packing Fraction
0.5240

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
18.61 4.7667 1.0 (1,0,0)
22.84 3.8930 1.3 (0,1,-3)
23.94 3.7177 97.2 (1,1,0)
24.52 3.6298 95.5 (1,-1,0)
29.22 3.0561 100.0 (1,1,3)
29.48 3.0297 95.5 (1,1,-3)
29.77 3.0009 97.9 (1,-1,3)
29.91 2.9873 92.8 (1,-1,-3)
31.04 2.8813 13.0 (0,2,0)
33.85 2.6480 39.3 (0,0,6)
35.42 2.5344 34.0 (0,2,3)
35.52 2.5275 30.9 (0,2,-3)
37.40 2.4046 1.1 (1,1,-5)
37.74 2.3836 1.3 (1,2,2)
37.74 2.3833 9.7 (2,0,0)
38.75 2.3238 19.8 (1,0,6)
39.06 2.3059 20.7 (1,0,-6)
39.85 2.2621 21.5 (1,2,3)
40.10 2.2489 22.2 (1,2,-3)
40.69 2.2175 21.9 (1,-2,3)
40.75 2.2143 20.2 (1,-2,-3)
41.69 2.1663 16.6 (1,1,6)
42.08 2.1475 11.5 (1,1,-6)
42.14 2.1442 14.5 (1,-1,6)
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Energy Properties

Formation Energy/atom
-2.54638
eV/atom
Energy/atom
-7.46660
eV/atom
Energy above Hull
0.0865
eV/atom
Uncorrected Energy
-6.5589
eV/atom
Volume/atom
12.13
ų
c/a Ratio
-

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
53.0011
μB
Mag. Ordering
FM
Mag. Sites
12
Magnetization/Volume
0.121410
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
F · 0.472
Element Family
Metalloid-Nonmetal
Solute Fraction
0.528
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
1.0389
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
8.6377
J/mol·K
Ω Parameter
0.0000
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
45.251%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
1.0899
smaller = more stable mixing
VEC
5.472
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
0.000
kJ/mol; negative = exothermic mixing
Entropy Norm
0.9457
SS Former
0
Phase Tendency
IM

Traditional Material Features

ROM Blended-Feature Radar
Rating & Classification
Tier
C
Score
0.412
Family
F-rich Multi-Component
Matrix Element
F · 0.472

Related Tasks

Related computation task IDs (1)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-760898
Reference Citation

The crystal structure and related material properties of Mn12O7F17 were obtained from the Materials Project database (MP-ID: mp-760898, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_Mn12O7F17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.76830200
_cell_length_b   5.76432795
_cell_length_c   15.88855464
_cell_angle_alpha   89.80035208
_cell_angle_beta   89.47258543
_cell_angle_gamma   88.60397794
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn12O7F17
_chemical_formula_sum   'Mn12 O7 F17'
_cell_volume   436.56326805
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.99200400  0.15585600  0.41511600  1.0
  Mn  Mn1  1  0.02846600  0.83876900  0.23804200  1.0
  Mn  Mn2  1  0.00966700  0.15996600  0.07556100  1.0
  Mn  Mn3  1  0.05222300  0.17136600  0.74924500  1.0
  Mn  Mn4  1  0.02243600  0.85351400  0.58064100  1.0
  Mn  Mn5  1  0.00093800  0.85758700  0.91845700  1.0
  Mn  Mn6  1  0.47342900  0.32111900  0.58505500  1.0
  Mn  Mn7  1  0.49058700  0.33068900  0.92359600  1.0
  Mn  Mn8  1  0.52990500  0.34083600  0.25936100  1.0
  Mn  Mn9  1  0.48676200  0.64949200  0.08240700  1.0
  Mn  Mn10  1  0.50319500  0.66554200  0.42041000  1.0
  Mn  Mn11  1  0.51012300  0.63083700  0.75506200  1.0
  O  O12  1  0.21124300  0.09699500  0.63990000  1.0
  O  O13  1  0.20636400  0.12173000  0.96892900  1.0
  O  O14  1  0.23027800  0.88858000  0.12725900  1.0
  O  O15  1  0.21611000  0.89927800  0.46859900  1.0
  O  O16  1  0.30569100  0.38797400  0.80984200  1.0
  O  O17  1  0.70082300  0.38260800  0.02948600  1.0
  O  O18  1  0.72737900  0.38706400  0.36885700  1.0
  F  F19  1  0.22497600  0.11840200  0.30591400  1.0
  F  F20  1  0.25002300  0.87642700  0.80711700  1.0
  F  F21  1  0.26713900  0.39608800  0.15093000  1.0
  F  F22  1  0.27778800  0.61859900  0.30968500  1.0
  F  F23  1  0.24515700  0.40060800  0.47359400  1.0
  F  F24  1  0.26466400  0.60259100  0.64521800  1.0
  F  F25  1  0.24948600  0.61457900  0.97644900  1.0
  F  F26  1  0.72375200  0.61880000  0.19267100  1.0
  F  F27  1  0.72600200  0.62576800  0.53319600  1.0
  F  F28  1  0.73871800  0.61422600  0.86723500  1.0
  F  F29  1  0.74078400  0.38001400  0.69288600  1.0
  F  F30  1  0.78827000  0.12569200  0.18634500  1.0
  F  F31  1  0.75363000  0.11434500  0.52065700  1.0
  F  F32  1  0.76392600  0.89195400  0.35072100  1.0
  F  F33  1  0.73756700  0.88230900  0.02380400  1.0
  F  F34  1  0.78390600  0.12028000  0.85102800  1.0
  F  F35  1  0.76658500  0.85951900  0.69672400  1.0
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