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Mn2OF3

High-Entropy Materials HEA Traditional Materials TRA

MP-ID: mp-777326 · Space group: Amm2 (#38)

Basic Information

Formula
Mn2OF3
MP-ID
mp-777326
Elements
3
Sites
24
Density
4.0259
g/cm³
Volume
301.71
ų
Cell a
4.8717
Å
Cell b
4.8717
Å
Cell c
12.7352
Å
α Angle
90.00
°
β Angle
90.00
°
γ Angle
93.42
°
Space Group
Amm2
Point Group
mm2
Crystal System
Orthorhombic
Bravais Lattice
Orthorhombic P
Stability
No
Packing Fraction
0.5240

X-ray Diffraction

Diffraction Pattern
X-axis: 2θ (°); Y-axis: relative intensity; CuKa ; λ=1.5406 Å
Diffraction Peaks (Top 24)
2θd (Å)Ihkl
25.11 3.5460 100.0 (1,-1,0)
26.69 3.3405 89.2 (1,1,0)
33.65 2.6637 97.6 (1,0,4)
36.97 2.4315 12.6 (2,0,0)
37.98 2.3690 20.5 (1,-1,4)
39.08 2.3047 20.4 (1,1,4)
40.48 2.2286 7.6 (2,-1,0)
42.55 2.1247 5.2 (2,1,0)
43.17 2.0958 3.4 (2,1,1)
44.98 2.0155 3.2 (2,1,2)
49.95 1.8258 67.6 (2,-1,4)
51.55 1.7730 21.1 (2,-2,0)
51.72 1.7673 50.0 (2,1,4)
54.98 1.6703 14.4 (2,2,0)
57.93 1.5919 19.3 (0,0,8)
58.78 1.5709 1.3 (3,0,2)
58.98 1.5661 9.8 (3,-1,0)
61.35 1.5110 6.2 (3,1,0)
61.78 1.5016 1.1 (2,1,6)
62.83 1.4791 1.6 (2,2,4)
64.12 1.4523 11.5 (1,-1,8)
64.51 1.4446 41.8 (3,0,4)
64.89 1.4371 11.8 (1,1,8)
65.58 1.4235 1.0 (3,1,3)
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Energy Properties

Formation Energy/atom
-2.62091
eV/atom
Energy/atom
-7.45687
eV/atom
Energy above Hull
0.0596
eV/atom
Uncorrected Energy
-6.5554
eV/atom
Volume/atom
12.57
ų
c/a Ratio
-

Electronic Properties

Metallic
Metal
Band Gap
0
eV
Direct Gap
No
CBM
N/A
eV

Magnetic Properties

Magnetic
Yes
Total Mag. Moment
36.0018
μB
Mag. Ordering
FM
Mag. Sites
8
Magnetization/Volume
0.119330
μB/ų

Elastic Properties

Elastic data not available

Feature Analysis

Composition Overview

Element Composition (atomic fraction)
Composition Info
Major / Matrix Element
F · 0.500
Element Family
Metalloid-Nonmetal
Solute Fraction
0.500
Interstitial Fraction
0.000

High-Entropy Alloy Features

Composite Radar (normalized)
Element-Class Share
Mix Entropy ΔS/R
1.0114
HEA criterion (>1.0 = high entropy)
Mix Entropy ΔS
8.4088
J/mol·K
Ω Parameter
0.0000
Ω > 1.1 favors solid solution
Atomic Size Mismatch δr
45.643%
δr < 6.6% favors single-phase solid solution
Electronegativity Diff Δχ
1.0986
smaller = more stable mixing
VEC
5.500
valence electron concentration, affects phase stability
Mix Enthalpy ΔH_mix
0.000
kJ/mol; negative = exothermic mixing
Entropy Norm
0.9206
SS Former
0
Phase Tendency
IM

Traditional Material Features

ROM Blended-Feature Radar
Rating & Classification
Tier
B
Score
0.452
Family
F-rich Multi-Component
Matrix Element
F · 0.500

Related Tasks

Related computation task IDs (2)

Citation & References

Materials Project Page
https://materialsproject.org/materials/mp-777326
Reference Citation

The crystal structure and related material properties of Mn2OF3 were obtained from the Materials Project database (MP-ID: mp-777326, database version v2026.04.13).

Literature Citation

Horton, M.K., Huck, P., Yang, R.X. et al. Accelerated data-driven materials science with the Materials Project. Nat. Mater. 24, 1522–1532 (2025). https://doi.org/10.1038/s41563-025-02272-0

BibTeX
@article{Horton2025,
  author  = {Horton, Matthew K. and Huck, Patrick and Yang, Ruo Xi and Munro, Jason M. and Dwaraknath, Shyam and Ganose, Alex M. and Kingsbury, Ryan S. and Wen, Mingjian and Shen, Jimmy X. and Mathis, Tyler S. and Kaplan, Aaron D. and Berket, Karlo and Riebesell, Janosh and George, Janine and Rosen, Andrew S. and Spotte-Smith, Evan W. C. and McDermott, Matthew J. and Cohen, Orion A. and Dunn, Alex and Kuner, Matthew C. and Rignanese, Gian-Marco and Petretto, Guido and Waroquiers, David and Griffin, Sinead M. and Neaton, Jeffrey B. and Chrzan, Daryl C. and Asta, Mark and Hautier, Geoffroy and Cholia, Shreyas and Ceder, Gerbrand and Ong, Shyue Ping and Jain, Anubhav and Persson, Kristin A.},
  title   = {Accelerated data-driven materials science with the Materials Project},
  journal = {Nature Materials},
  year    = {2025},
  volume  = {24},
  number  = {10},
  pages   = {1522--1532},
  month   = {oct},
  doi     = {10.1038/s41563-025-02272-0},
  issn    = {1476-4660},
  url     = {https://doi.org/10.1038/s41563-025-02272-0},
  abstract = {The Materials Project was launched formally in 2011 to drive materials discovery forwards through high-throughput computation and open data. More than a decade later, the Materials Project has become an indispensable tool used by more than 600,000 materials researchers around the world. This Perspective describes how the Materials Project, as a data platform and a software ecosystem, has helped to shape research in data-driven materials science. We cover how sustainable software and computational methods have accelerated materials design while becoming more open source and collaborative in nature. Next, we present cases where the Materials Project was used to understand and discover functional materials. We then describe our efforts to meet the needs of an expanding user base, through technical infrastructure updates ranging from data architecture and cloud resources to interactive web applications. Finally, we discuss opportunities to better aid the research community, with the vision that more accessible and easy-to-understand materials data will result in democratized materials knowledge and an increasingly collaborative community.}
}

3D Crystal Structure Rendering

Loading 3D structure…

Style: Ball & Stick
Raw CIF Data
# generated using pymatgen
data_Mn2OF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.87168194
_cell_length_b   4.87168194
_cell_length_c   12.73520100
_cell_angle_alpha   90.00000000
_cell_angle_beta   90.00000000
_cell_angle_gamma   93.41861147
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Mn2OF3
_chemical_formula_sum   'Mn8 O4 F12'
_cell_volume   301.71030678
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.96391900  0.96391900  0.00000000  1.0
  Mn  Mn1  1  0.02318800  0.02318800  0.24906600  1.0
  Mn  Mn2  1  0.01622400  0.01622400  0.50000000  1.0
  Mn  Mn3  1  0.02318800  0.02318800  0.75093400  1.0
  Mn  Mn4  1  0.48549700  0.48549700  0.62529500  1.0
  Mn  Mn5  1  0.49540000  0.49540000  0.12485600  1.0
  Mn  Mn6  1  0.48549700  0.48549700  0.37470500  1.0
  Mn  Mn7  1  0.49540000  0.49540000  0.87514400  1.0
  O  O8  1  0.31869700  0.31869700  0.24682000  1.0
  O  O9  1  0.30697600  0.30697600  0.50000000  1.0
  O  O10  1  0.31869700  0.31869700  0.75318000  1.0
  O  O11  1  0.66653600  0.66653600  0.00000000  1.0
  F  F12  1  0.79419500  0.19588000  0.12520900  1.0
  F  F13  1  0.81231400  0.20032000  0.37576100  1.0
  F  F14  1  0.81231400  0.20032000  0.62423900  1.0
  F  F15  1  0.79419500  0.19588000  0.87479100  1.0
  F  F16  1  0.27814900  0.27814900  0.00000000  1.0
  F  F17  1  0.70778100  0.70778100  0.25521300  1.0
  F  F18  1  0.70165400  0.70165400  0.50000000  1.0
  F  F19  1  0.70778100  0.70778100  0.74478700  1.0
  F  F20  1  0.19588000  0.79419500  0.12520900  1.0
  F  F21  1  0.20032000  0.81231400  0.37576100  1.0
  F  F22  1  0.20032000  0.81231400  0.62423900  1.0
  F  F23  1  0.19588000  0.79419500  0.87479100  1.0
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